MID TEST

  MID TEST

ORGANIC CHEMISTRY I

DAY/ TIME          : TUESDAY, NOVEMBER 13TH 2012-11-13

LECTURE              : Dr. Syamsurizal

   

     1. A). explain how the concept of organic compounds from petroleum can be used as a fuel for vehicles such as car,motorbike, including aircraft?

      Answer:

     organic compounds from petroleum can be used as a fuel for vehicles. This can happen because of petroleum (crude oil) have been treated with a variety of processes, without being processed / processed oil is not at all bermampaat. Broadly speaking, a process that lasted for petroleum processing, namely:· The process of distillation, the distillation process based on differences in boiling point; process takes place in Column Distillation Atmospheric and Vacuum Distillation Column. In the second crude unit processes distilled into fractions, namely gas, light distillate (such as gasoline oil), middle distillates (such as kerosene, diesel oil), fuel oil (gas oil), and residues. Separation of fractions based on boiling point. Crude oil is vaporized in the distillation process, up to the top of the column and then condensed at different temperatures. Components of a higher boiling point will remain a liquid and fall to the bottom, while the lower boiling point will evaporate and rise to the top through the lid-lid-called bubble shield. Growing up, temperatures are in the fractionating column is getting low, so each time the component with a higher boiling point will be separated, while the component lower boiling point up to the more up again. So the next so that the component is a component that peaked at room temperature in the form of gas. Components in the form of gas is called petroleum gas, liquefied and then called LPG (Liquified Petroleum Gas).

    The process of conversion, which is a process to change the size and structure of hydrocarbon compounds. Included in this process are:· Decomposition by means of thermal and catalytic cracking (thermal and catalytic cracking)· Unification through alkylation and polymerization process· Alteration through isomerization and catalytic reforming process

    Treatment Process (treatment). This process is intended to prepare hydrocarbon fractions for further processing, also to be processed into the final product.
    Formulation and Blending (Blending), which is the process of mixing the hydrocarbon fractions and addition of additives to get the final product with a certain spec.Thus, through the processes of oil can be processed into fuel vehicles.

B) explain it how the idea of chemical compound from petroleum can be used to make clothing and plastic and material needs of other human lives ?

answer:

 chemical compounds from petroleum can be used to make clothing and plastic and other material of human life. This can occur due to chemical compounds from petroleum can be processed by a variety of processes that can produce fiber or plastic clothing and other necessities. For example, hydrocarbons can be processed for the life of such material for the manufacture of plastics and clothing and other necessities. Of hydrocarbon material that can be used for clothing is PTA (purified terephthalic acid), which is made of para-xylene in which the material is essentially kerosene (kerosene). Of kerosene is all the material formed into compound Aromat, the para-xylene. The form compounds benzene (C6H6), but there are two methyl groups at C1 and C3 atoms of the benzene molecule.Para-xylene is then oxidized using air into the PTA. PTA shaped like detergent powder is then reacted with methanol into polyester fibers. Fiber poly ester which is the synthetic yarn that looks like a thread. Almost all kind of uniform clothing may be made of polyester. To facilitate their identification can be seen from the price. Price clothing made of synthetic polyester yarns are usually relatively cheaper than clothing made from raw cotton, silk or other natural fibers. While plastics from petroleum comes from poliester.Poliester is a category of polymers which contain the ester functional group in the main chain. Although there are many polyesters, the term "polyester" is as a specific material more often refers to polyethylene terephthalate (PET). Polyesters include natural chemicals, such as those kutin of plant cuticles, as well as synthetic chemicals such as polycarbonate and polybutyrate.Can be produced in various shapes such as sheets and three-dimensional shapes, as thermoplastic polyesters can change shape after heated. While combustible at high temperatures, polyesters tend to wrinkle away from the fire and extinguish themselves during combustion. Polyester fibers have high strength and E-modulus and low water absorption and minimal shrinkage when compared to other industrial fibers.Tertenun polyester fabric used in consumer apparel and home furnishings such as bed sheets, bed covers, curtains and drapery. Industrial polyester used in tire reinforcements, ropes, fabrics for introductory machine belt (conveyor), safety belts, coated fabrics and plastic reinforcements with high energy absorption rate. Of polyester fiber fill is also used to fill pillows and blanket warmers.
Fabrics of polyester touted feels "unnatural" when compared with the same fabric woven from natural fibers (eg cotton in textile uses). But polyester fabric has several advantages such as increased resilience of shrinkage. As a result, polyester fibers are sometimes spun together with natural fibers to produce a shirt with combined properties.

Polyester is also used to make bottles, films, tarpaulin, canoes, liquid crystal displays, holograms, filters, saput (film) dielectrics for capacitors, saput insulation for wire and insulating tapes.
Liquid crystalline polyesters are one of the used liquid crystalline polymers industry first and used for their mechanical properties and resistance to heat. The advantage is important in its use as a seal capable of abrasion in jet engines.
Hot loud polyester (thermosetting) used as a foundry, and chemosetting polyester resin is used as a coating resin fiber glass and putty a non-metallic car bodies. Reinforced unsaturated polyester glass fiber widely used in the body of the cruise ship and car.
Polyester is also used extensively as a smoothing (finish) on a high quality wood products such as guitars, pianos and vehicle / yacht. Burns London company, Rolls-Royce and Sunseeker are a few companies that use polyesters to their products. Tiksotropi properties of polyester that can be used as a spray makes it ideal for use on open-grain timbers, as they can quickly fill wood grain, with a thickness that is formed with a strong saput per layer. Cured polyesters can be sanded and polished to a final product.

    2.       explain why the hydrocarbon that are asymetrical or chiral have a variety of benefit for human being.and sescribe how does it the chiral centers can be formed.

      Answer: 

    Chiral compounds of hydrocarbons is when four different ligands bound to the carbon tetravalent, asymmetric molecules which produce carbon atom at the center asimetrisnya produce asymmetric molecules in which the carbon atom at the center asimetrisnya. an organic molecule is called chiral molecules if there is at least one C atom that binds to four different groups amino.Molekul acid-like compound chiral molecules have the properties that are unique optical properties. That is a chiral molecule has the ability to rotate the plane of polarized light in a device called a polarimeter. chemical reactions in biological systems are very stereospecific living things. That is a stereoisomer will undergo a different reaction partner stereoisomers in biological systems of living things. In fact, sometimes a stereoisomer will produce different products with partner stereoisomers in biological systems of living things.
Chiral compounds are usually bermampaat for drugs
Chiral center formed in this way: Determine the priority order of 4 atoms / groups attached to C and chiral chiral centers viewed from the opposite direction with priority yangmempunyai atom / lowest group., If the order of priority (besarkecil) clockwise then the center has kiraldikatakan R. Otherwise configuration, the center has kiraldikatakan configuration S. Increasing atomic number, the higher the priority, for example: I> Br> Cl> F> OH> NH> CH 3> H
If any groups are identical, then the priority is determined by the number of the next atom.

1   3. when ethylene gas produced from a ripe fruit can be used to ripe other fruits that are still unripe.how do you idea when the gas is used as fuel gas like methane gas

  Answer:

As we know Methane is one of the fuels that are important in the generation of electricity, by burning it in a gas turbine or steam heating. Methane in the form of compressed natural gas used as vehicle fuel and has been proven as well as the fuel is more environmentally friendly than other fossil fuels range of petrol and diesel.
Ethylene gas is natural gas. This gas is a gaseous hormone in plant life active in ripening fruit. Applications containing Ethephon, the synthetic Ethylene optimal performance so that goals can be achieved pieces cook faster. (eg: Etephon, Protephon) trademarks include: Prothephon 480SL. Ethylene gas is found in many old fruit. This gas may be as methane gas when it is done with the addition of ethylene oxidation on many other elements. This really allows ethylene to ethylene gas as fuel is natural gas.

1  4. aromatic coumpound are marked by ease of adjacent electrons conjugated. please explain why ansaturated coumpound which highly conjugated but is not aromatic

  Answer:

a ring consisting of bond conjugated unsaturated bond, a single pair, or an empty orbit showed stronger stability than the stability of a system consisting only of conjugation. N ot only aromatic compounds having a conjugated electron adjacent but uga should have 6 carbon atoms connected by three single bonds and 3 double bonds that criss-crossUnsaturated aliphatic compounds are aliphatic compounds, varying chain C double bond or triple. coumpound roomates highly unsaturated conjugated aromatic but is not due to absorption in the ith position mspektrum determine the number of protons bound to the atom-atom ring. Proton-bound outward terperisai aromatic rings are very strong and absorbs far down-field than most protons, usually more than 7 ppm.

ACID AND BASES ORGANIC

THE ACIDITY OF ORGANIC ACIDS This page explains the acidity of simple organic acids and looks at the factors which affect their relative strengths. Why are organic acids acidic? Organic acids as weak acids For the purposes of this topic, we are going to take the definition of an acid as "a substance which donates hydrogen ions (protons) to other things". We are going to get a measure of this by looking at how easily the acids release hydrogen ions to water molecules when they are in solution in water. An acid in solution sets up this equilibrium:
	Note:  We are writing the acid as AH rather than HA, because, in all the cases we shall be looking at, the hydrogen we are interested in is at the right-hand end of a molecule.
A hydroxonium ion is formed together with the anion (negative ion) from the acid. This equilibrium is sometimes simplified by leaving out the water to emphasise the ionisation of the acid. If you write it like this, you must include the state symbols - "(aq)". Writing H+(aq) implies that the hydrogen ion is attached to a water molecule as H3O+. Hydrogen ions are always attached to something during chemical reactions. The organic acids are weak in the sense that this ionisation is very incomplete. At any one time, most of the acid will be present in the solution as un-ionised molecules. For example, in the case of dilute ethanoic acid, the solution contains about 99% of ethanoic acid molecules - at any instant, only about 1% have actually ionised. The position of equilibrium therefore lies well to the left. Comparing the strengths of weak acids The strengths of weak acids are measured on the pKa scale. The smaller the number on this scale, the stronger the acid is. Three of the compounds we shall be looking at, together with their pKa values are: Remember - the smaller the number the stronger the acid. Comparing the other two to ethanoic acid, you will see that phenol is very much weaker with a pKa of 10.00, and ethanol is so weak with a pKa of about 16 that it hardly counts as acidic at all! Why are these acids acidic? In each case, the same bond gets broken - the bond between the hydrogen and oxygen in an -OH group. Writing the rest of the molecule as "X":
	Note:  If you aren't sure about coordinate covalent (dative covalent) bonding, you might like to follow this link. It isn't, however, particularly important to the rest of the current page. Use the BACK button on your browser to return to this page later.
So . . . if the same bond is being broken in each case, why do these three compounds have such widely different acid strengths? Differences in acid strengths between carboxylic acids, phenols and alcohols The factors to consider Two of the factors which influence the ionisation of an acid are: the strength of the bond being broken, the stability of the ions being formed. In these cases, you seem to be breaking the same oxygen-hydrogen bond each time, and so you might expect the strengths to be similar.
	Note:  You've got to be a bit careful about this. The bonds won't be identically strong, because what's around them in the molecule isn't the same in each case.
The most important factor in determining the relative acid strengths of these molecules is the nature of the ions formed. You always get a hydroxonium ion - so that's constant - but the nature of the anion (the negative ion) varies markedly from case to case. Ethanoic acid Ethanoic acid has the structure: The acidic hydrogen is the one attached to the oxygen. When ethanoic acid ionises it forms the ethanoate ion, CH3COO-. You might reasonably suppose that the structure of the ethanoate ion was as below, but measurements of bond lengths show that the two carbon-oxygen bonds are identical and somewhere in length between a single and a double bond. To understand why this is, you have to look in some detail at the bonding in the ethanoate ion.
	Warning!  If you don't already understand about the bonding in the carbon-oxygen double bond, you would be well advised to skip this next bit - all the way down to the simplified structure of the ethanoate ion towards the end of it. It goes beyond anything that you are likely to want for UK A level purposes. If you do choose to follow this link, it will probably take you to several other pages before you are ready to come back here again. Use the BACK button (or HISTORY file or GO menu) on your browser to return to this page.
Like any other double bond, a carbon-oxygen double bond is made up of two different parts. One electron pair is found on the line between the two nuclei - this is known as a sigma bond. The other electron pair is found above and below the plane of the molecule in a pi bond. Pi bonds are made by sideways overlap between p orbitals on the carbon and the oxygen. In an ethanoate ion, one of the lone pairs on the negative oxygen ends up almost parallel to these p orbitals, and overlaps with them. This leads to a delocalised pi system over the whole of the -COO- group, rather like that in benzene. All the oxygen lone pairs have been left out of this diagram to avoid confusion. Because the oxygens are more electronegative than the carbon, the delocalised system is heavily distorted so that the electrons spend much more time in the region of the oxygen atoms. So where is the negative charge in all this? It has been spread around over the whole of the -COO- group, but with the greatest chance of finding it in the region of the two oxygen atoms. Ethanoate ions can be drawn simply as: The dotted line represents the delocalisation. The negative charge is written centrally on that end of the molecule to show that it isn't localised on one of the oxygen atoms. The more you can spread charge around, the more stable an ion becomes. In this case, if you delocalise the negative charge over several atoms, it is going to be much less attractive to hydrogen ions - and so you are less likely to re-form the ethanoic acid. Phenol Phenols have an -OH group attached directly to a benzene ring. Phenol itself is the simplest of these with nothing else attached to the ring apart from the -OH group. When the hydrogen-oxygen bond in phenol breaks, you get a phenoxide ion, C6H5O-.
	Warning!  You need to understand about the bonding in benzene in order to make sense of this next bit. If your syllabus says that you need to know about the acidity of phenol, then you will have to understand the next few paragraphs - which in turn means that you will have to understand about benzene. If it doesn't mention phenol, skip it! If you follow this link, you may have to explore several other pages before you are ready to come back here again. Use the BACK button (or HISTORY file or GO menu) on your browser to return to this page.
Delocalisation also occurs in this ion. This time, one of the lone pairs on the oxygen atom overlaps with the delocalised electrons on the benzene ring. This overlap leads to a delocalisation which extends from the ring out over the oxygen atom. As a result, the negative charge is no longer entirely localised on the oxygen, but is spread out around the whole ion. Why then is phenol a much weaker acid than ethanoic acid? Think about the ethanoate ion again. If there wasn't any delocalisation, the charge would all be on one of the oxygen atoms, like this: But the delocalisation spreads this charge over the whole of the COO group. Because oxygen is more electronegative than carbon, you can think of most of the charge being shared between the two oxygens (shown by the heavy red shading in this diagram). If there wasn't any delocalisation, one of the oxygens would have a full charge which would be very attractive towards hydrogen ions. With delocalisation, that charge is spread over two oxygen atoms, and neither will be as attractive to a hydrogen ion as if one of the oxygens carried the whole charge. That means that the ethanoate ion won't take up a hydrogen ion as easily as it would if there wasn't any delocalisation. Because some of it stays ionised, the formation of the hydrogen ions means that it is acidic. In the phenoxide ion, the single oxygen atom is still the most electronegative thing present, and the delocalised system will be heavily distorted towards it. That still leaves the oxygen atom with most of its negative charge. What delocalisation there is makes the phenoxide ion more stable than it would otherwise be, and so phenol is acidic to an extent. However, the delocalisation hasn't shared the charge around very effectively. There is still lots of negative charge around the oxygen to which hydrogen ions will be attracted - and so the phenol will readily re-form. Phenol is therefore only very weakly acidic. Ethanol Ethanol, CH3CH2OH, is so weakly acidic that you would hardly count it as acidic at all. If the hydrogen-oxygen bond breaks to release a hydrogen ion, an ethoxide ion is formed: This has nothing at all going for it. There is no way of delocalising the negative charge, which remains firmly on the oxygen atom. That intense negative charge will be highly attractive towards hydrogen ions, and so the ethanol will instantly re-form. Since ethanol is very poor at losing hydrogen ions, it is hardly acidic at all. Variations in acid strengths between different carboxylic acids You might think that all carboxylic acids would have the same strength because each depends on the delocalisation of the negative charge around the -COO- group to make the anion more stable, and so more reluctant to re-combine with a hydrogen ion. In fact, the carboxylic acids have widely different acidities. One obvious difference is between methanoic acid, HCOOH, and the other simple carboxylic acids: pKa HCOOH 3.75 CH3COOH 4.76 CH3CH2COOH 4.87 CH3CH2CH2COOH 4.82 Remember that the higher the value for pKa, the weaker the acid is. Why is ethanoic acid weaker than methanoic acid? It again depends on the stability of the anions formed - on how much it is possible to delocalise the negative charge. The less the charge is delocalised, the less stable the ion, and the weaker the acid. The methanoate ion (from methanoic acid) is: The only difference between this and the ethanoate ion is the presence of the CH3 group in the ethanoate. But that's important! Alkyl groups have a tendency to "push" electrons away from themselves. That means that there will be a small amount of extra negative charge built up on the -COO- group. Any build-up of charge will make the ion less stable, and more attractive to hydrogen ions. Ethanoic acid is therefore weaker than methanoic acid, because it will re-form more easily from its ions. The other alkyl groups have "electron-pushing" effects very similar to the methyl group, and so the strengths of propanoic acid and butanoic acid are very similar to ethanoic acid.
	Note:  If you want more information about the inductive effect of alkyl groups, you could read about carbocations (carbonium ions) in the mechanism section of this site. Use the BACK button on your browser to return to this page if you choose to follow this link.
The acids can be strengthened by pulling charge away from the -COO- end. You can do this by attaching electronegative atoms like chlorine to the chain. As the next table shows, the more chlorines you can attach the better: pKa CH3COOH 4.76 CH2ClCOOH 2.86 CHCl2COOH 1.29 CCl3COOH 0.65 Trichloroethanoic acid is quite a strong acid. Attaching different halogens also makes a difference. Fluorine is the most electronegative and so you would expect it to be most successful at pulling charge away from the -COO- end and so strengthening the acid. pKa CH2FCOOH 2.66 CH2ClCOOH 2.86 CH2BrCOOH 2.90 CH2ICOOH 3.17 The effect is there, but isn't as great as you might expect. Finally, notice that the effect falls off quite quickly as the attached halogen gets further away from the -COO- end. Here is what happens if you move a chlorine atom along the chain in butanoic acid. pKa CH3CH2CH2COOH 4.82 CH3CH2CHClCOOH 2.84 CH3CHClCH2COOH 4.06 CH2ClCH2CH2COOH 4.52 The chlorine is effective at withdrawing charge when it is next-door to the -COO- group, and much less so as it gets even one carbon further away. ORGANIC BASES This page explains why simple organic bases are basic and looks at the factors which affect their relative strengths. For A'level purposes, all the bases we are concerned with are primary amines - compounds in which one of the hydrogens in an ammonia molecule, NH3, is replaced either by an alkyl group or a benzene ring. Why are primary amines basic? Ammonia as a weak base All of the compounds we are concerned with are derived from ammonia and so we'll start by looking at the reason for its basic properties. For the purposes of this topic, we are going to take the definition of a base as "a substance which combines with hydrogen ions (protons)". We are going to get a measure of this by looking at how easily the bases take hydrogen ions from water molecules when they are in solution in water. Ammonia in solution sets up this equilibrium: An ammonium ion is formed together with hydroxide ions. Because the ammonia is only a weak base, it doesn't hang on to the extra hydrogen ion very effectively and so the reaction is reversible. At any one time, about 99% of the ammonia is present as unreacted molecules. The position of equilibrium lies well to the left. The ammonia reacts as a base because of the active lone pair on the nitrogen. Nitrogen is more electronegative than hydrogen and so attracts the bonding electrons in the ammonia molecule towards itself. That means that in addition to the lone pair, there is a build-up of negative charge around the nitrogen atom. That combination of extra negativity and active lone pair attracts the new hydrogen from the water. Comparing the strengths of weak bases The strengths of weak bases are measured on the pKb scale. The smaller the number on this scale, the stronger the base is. Three of the compounds we shall be looking at, together with their pKb values are: Remember - the smaller the number the stronger the base. Comparing the other two to ammonia, you will see that methylamine is a stronger base, whereas phenylamine is very much weaker. Methylamine is typical of aliphatic primary amines - where the -NH2 group is attached to a carbon chain. All aliphatic primary amines are stronger bases than ammonia. Phenylamine is typical of aromatic primary amines - where the -NH2 group is attached directly to a benzene ring. These are very much weaker bases than ammonia. Explaining the differences in base strengths The factors to consider Two of the factors which influence the strength of a base are: the ease with which the lone pair picks up a hydrogen ion, the stability of the ions being formed. Why are aliphatic primary amines stronger bases than ammonia? Methylamine Methylamine has the structure: The only difference between this and ammonia is the presence of the CH3 group in the methylamine. But that's important! Alkyl groups have a tendency to "push" electrons away from themselves. That means that there will be a small amount of extra negative charge built up on the nitrogen atom. That extra negativity around the nitrogen makes the lone pair even more attractive towards hydrogen ions. Making the nitrogen more negative helps the lone pair to pick up a hydrogen ion. What about the effect on the positive methylammonium ion formed? Is this more stable than a simple ammonium ion? Compare the methylammonium ion with an ammonium ion: In the methylammonium ion, the positive charge is spread around the ion by the "electron-pushing" effect of the methyl group. The more you can spread charge around, the more stable an ion becomes. In the ammonium ion there isn't any way of spreading the charge. To summarise: The nitrogen is more negative in methylamine than in ammonia, and so it picks up a hydrogen ion more readily. The ion formed from methylamine is more stable than the one formed from ammonia, and so is less likely to shed the hydrogen ion again. Taken together, these mean that methylamine is a stronger base than ammonia. Note:  This is a bit of a simplification for A' level purposes. As bases get more complex, another factor concerning the stability of the ions formed becomes important. That concerns the way they interact with water molecules in the solution. You don't need to worry about that at this level. The other aliphatic primary amines The other alkyl groups have "electron-pushing" effects very similar to the methyl group, and so the strengths of the other aliphatic primary amines are very similar to methylamine. Note:  If you want more information about the inductive effect of alkyl groups, you could read about carbocations (carbonium ions) in the mechanism section of this site. For example: pKb CH3NH2 3.36 CH3CH2NH2 3.27 CH3CH2CH2NH2 3.16 CH3CH2CH2CH2NH2 3.39 Why are aromatic primary amines much weaker bases than ammonia? An aromatic primary amine is one in which the -NH2 group is attached directly to a benzene ring. The only one you are likely to come across is phenylamine. Phenylamine has the structure: The lone pair on the nitrogen touches the delocalised ring electrons . . . . . . and becomes delocalised with them: That means that the lone pair is no longer fully available to combine with hydrogen ions. The nitrogen is still the most electronegative atom in the molecule, and so the delocalised electrons will be attracted towards it, but the intensity of charge around the nitrogen is nothing like what it is in, say, an ammonia molecule. The other problem is that if the lone pair is used to join to a hydrogen ion, it is no longer available to contribute to the delocalisation. That means that the delocalisation would have to be disrupted if the phenylamine acts as a base. Delocalisation makes molecules more stable, and so disrupting the delocalisation costs energy and won't happen easily. Taken together - the lack of intense charge around the nitrogen, and the need to break some delocalisation - this means that phenylamine is a very weak base indeed. Organic acids are compounds of carbon generated acid plants and animals naturally. Most of this acid is a weak acid that is not dangerous and give flavor to many fruits and foods. some examples of organic acids 1) Aspirin or acetylsalicylic acid (aspirin) is a salicylate drug family that is often used as an analgesic (against minor pains or aches), antipyretic (against fever), and anti-inflammatory. Aspirin also has anticoagulant effect and is used in low doses in a long time to prevent a heart attack. The origin of the drug known as "aspirin" - apparently from ancient Greece, and was introduced by Mr. Doctor entire world - that Hippocrates. Of course no mention of Hippocrates Aspirin, but mentions named willow plants when stems are dried and used as a powder, it can relieve pain. Thousands of years passed, until in 1829, scientists succeeded in isolating an ingredient in willow plants which serve to relieve the pain. The material is called salicin. This material may relieve pain, but have side effects on the stomach - the same great benefits and harm. Of course there must be a way out. In 1853, a French chemist named Charles Frederic Gerhardt managed to neutralize the natural salicin into salicylic acid (salicylic acid) through buffering (buffering) with sodium and acetic acid. Salicylic acid is more "friendly" to the stomach. In 1899, a German chemist, named Felix Hoffmann, working for Bayer, rediscovered Gerhardt's formula. Hoffmann persuade Bayer to market the drug, which later appeared on the market with the market name "Aspirin". Aspirin was the first drug marketed in tablet form. Previously, the drug trade in the form of powder (powder). In welcoming the 2006 FIFA World Cup in Germany, a replica of a giant aspirin tablets on display in Berlin as part of the exhibition is open Deutschland, Land der Ideen. 2) Formic acid (systematic name: metanoat acid) is the simplest carboxylic acid. Formic acid is naturally present in the sting include bees and ants. Formic acid is also an intermediate compound (intermediate) are important in many chemical synthesis. The formula can be written as formic acid HCOOH or CH2O2. In nature, formic acid found in many insect stings and bites of the order Hymenoptera, such as bees and ants. Formic acid is also a significant combustion of alternative fuels, the burning methanol (and ethanol were mixed with water), when mixed with gasoline. Name of formic acid derived from the Latin word meaning ant Formica. At first, this compound was isolated by distillation of ants. Formic acid derivatives of chemical compounds, such as salt and ester groups, called format or metanoat. Ion format has a chemical formula HCOO-. 3) pyruvic acid (CH3COCO2H) is an alpha-keto acid which has an important role in biochemical processes. Carboxylate anion of pyruvic acid called pyruvate. Pyruvic acid is a colorless liquid with an odor similar to acetic acid. Pyruvic acid mixed with water, and soluble in ethanol and diethyl ether. In the laboratory, pyruvic acid is made by heating a mixture of tartaric acid with potassium bisulfate, or by hydrolysis of acetyl cyanide, which is made by reaction of acetyl chloride and potassium cyanide. Pyruvate is an important chemical compound in biochemistry. This compound is the metabolism of glucose is called glycolysis. A glucose molecule is split into two molecules of pyruvic acid, which is then used to generate energy. If there is enough oxygen, the pyruvic acid is converted to acetyl-CoA, which is then processed in the Krebs cycle. Pyruvate can also be converted into oxaloacetate by reaction anaploretik were then broken down into molecules of carbon dioxide. Cycle name is taken from the biochemist Hans Adolf Krebs, winner of the 1953 Nobel Prize in Physiology, as he managed to identify the cycle). If there is not enough oxygen, pyruvic acid is broken down anaerobically, producing lactic acid in animals and humans, or ethanol in plants. Pyruvate is converted into lactate using the enzyme lactate dehydrogenase and the coenzyme NADH through lactate fermentation, or to acetaldehyde and then ethanol through fermentation alcohol. Pyruvic acid can also be converted to carbohydrates via gluconeogenesis, to fatty acids or energy through acetyl-CoA, to the amino acid alanine and to ethanol. Pyruvic acid derivatives, 3-bromopiruvat been studied for the treatment of cancer. 4) acetic acid, ethanoic acid or acetic acid is an organic acid chemical compounds known as sour flavoring and aroma in food. Acetic acid has the empirical formula C2H4O2. This formula is often written in the form of CH3-COOH, CH3COOH, or CH3CO2H. Pure acetic acid (called glacial acetic acid) is a colorless hygroscopic liquid, and has a freezing point of 16.7 ° C. Acetic acid is one of the simplest carboxylic acids, as formic acid. Solution of acetic acid in water is a weak acid, meaning that only partially dissociate into H + and CH3COO-. Acetic acid is a chemical reagent and industrial raw materials is important. Acetic acid is used in the production of polymers such as polyethylene terephthalate, cellulose acetate and polyvinyl acetate, as well as a wide range of fibers and fabrics. In the food industry, acetic acid is used as an acidity regulator. In households, diluted acetic acid is often used as a water softener. Within a year, world demand for acetic acid to 6.5 million tons per year. 1.5 million tons per year generated from the recycling, the remainder derived from the petrochemical industry as well as from biological sources. Acetic acid is a trivial name or trade name of this compound, and is the name most recommended by IUPAC. The name is derived from the Latin word acetum, meaning vinegar. Systematic name of this compound is ethanoic acid. Glacial acetic acid is a trivial name that refers to acetic acid which is not mixed with water. So called because water-free acetic acid forms crystals resemble ice at 16.7 ° C, slightly below room temperature. The most commonly used abbreviations and acronyms merupakat official for acetic acid is AcOH or HOAc where Ac means an acetyl group, CH3-C (= O) -. In the context of acid-base, acetic acid is often abbreviated HAC, though many feel that the abbreviation is not true. Ac also not be confused with the symbol of the element actinium (Ac). 5) Oxalic acid is a chemical compound with the formula H2C2O4 with the systematic name etanadioat acid. Dicarboxylic acid is commonly described by the formula HOOC-COOH. Is a relatively strong organic acid, 10,000 times stronger than acetic acid. In-anion, known as oxalate, also pereduktor agent. Many metal ions form insoluble precipitate with oxalic acid, the best example is calcium oxalate (CaOOC-COOCa), the main constituent types of kidney stones are often found. MY PROBLEM why acetic is classified secure against the body, whereas acetic acid is accelerate corrosive to metals and soften iron ?