Sunday, September 30, 2012

HYDROCARBON



Question: Why do carbon atoms form bonds not only one but also can form a double bond or triple bond?

CARBON
 One of the privileges of carbon that is not owned by the other elements is their ability to form chains of carbon atoms, which we hereafter refer to as the carbon chain.

Carbon chains may be either a single bond, double bond, or a triple bond. Forms of carbon chains themselves are very varied, there is a straight (unbranched), there is a branching, there are open, and there is a closed (circular). Various forms of carbon chains presented in the figure below.

Compounds with an open chain compounds called aliphatic compounds while closed or circular chain called cyclic compounds. The compounds are all carbon bond is a single bond, - C - C - called unsaturated carbon compounds, while having a carbon-carbon double bond, - C - C -, or triple - C = C -, called unsaturated carbon compounds.

Cyclic compounds having conjugated bonds, the carbon-carbon bond alternating single and dual, are called aromatic compounds. All cyclic compounds that are not included aromatic compounds are called alicyclic compounds, (the word comes from the word ali alicyclic and cyclic). These compounds are called alicyclic compound because it has a circular shape, but its properties resemble aliphatic compounds.


Why carbon can form so many compounds, with very varied types? Why is this not happening in the adjacent element or elements are classified with the carbon in the periodic table? BC has the electron configuration of atoms 2 4. The four valence electrons distributed on the four C atoms in a symmetrical position.

The ability to bind carbon atoms and follow the octet rule is different from other atoms, even within a single class. For example, boron and nitrogen atoms. Electron configuration of two atoms is J3: 2 3 and _n: 2 5. Boron atom has three valence electrons so that when the covalent bonds, resulting compounds do not follow the octet Kaidan. Note the Lewis structure of the compound following BH3!

The compound BH, has the form of a symmetrical molecule and has three covalent bonds. In contrast to compound BH3, NH3 compounds follow the octet rule, but the shape of the molecule is not symmetrical because there is a lone pair.


Thus, compounds BH, and NH3 only has three covalent bonds. What about silicon? The silicon atom has an electron configuration 2 8 4. The silicon atom has four valence electrons with the carbon atom. The four electrons in the silicon atom is distributed on four sides symmetrically. Consider the Lewis structure of the following compound?


Note the Lewis structure and bonding in compounds SiH4 and SiO,. Lewis Structure and bonding in compounds such as CH4 and CO,. So, what are the differences?
Valence electrons in a silicon atom is located on the third skin, while the valence electrons in the carbon atom located on a second skin. Thus the Si atom radius greater than the radius of the atom C. Thus, the bonding Si - H to the compound anyway ^ weaker than the C - H in the compound CH4.


The carbon atom has four valence electrons with the atomic radii price the smallest of the atomic radius of other elements in the group IVA. It facilitates the C atom to form covalent bonds with other atoms, especially with atomic H, O, N, and halogen atoms (F, Cl, Br, and I). Covalent bonds are formed to meet the octet rule. The carbon atom can form up to four covalent bonds. Covalent bond formed by atoms C is more powerful than other covalent bonds, so that the carbon compounds are stable.

The position of carbon atoms in the periodic table in the middle so it has a moderate electronegativity value (2.5). This trait causes the carbon atoms can bind atoms having electronegativity greater or even smaller. The carbon atom can have a positive oxidation state (+2, +4), negative (-2, -4), or even zero.

Friday, September 28, 2012

Petroleum

What Is Petroleum?

Petroleum is a fossil fuel. It is called a fossil fuel because it was formed from the remains of tiny sea plants and animals that died millions of years ago. When the plants and animals died, they sank to the bottom of the oceans. They were buried by thousands of feet of sand and silt.
Over time, this organic mixture was subjected to enormous pressure and heat as the layers increased. The mixture changed chemically, breaking down into compounds made of hydrogen and carbon atoms—hydrocarbons. Finally, an oil-saturated rock—much like a wet household sponge—was formed.
All organic material does not turn into oil. Certain geological conditions must exist within the oil-rich rocks. First, there must be a trap of non-porous rock that prevents the oil from seeping out, and a seal (such as salt or clay) that keeps the oil from rising to the surface. Even under these conditions, only about two percent of the organic material is transformed into oil.
A typical petroleum reservoir is mostly sandstone or limestone in which oil is trapped. The oil in it may be as thin as gasoline or as thick as tar. It may be almost clear or black.
Petroleum is called a nonrenewable energy source because it takes millions of years to form. We cannot make more petroleum in a short time.

History of Oil

People have used naturally available petroleum since ancient times, though they didn’t know how to find it. The ancient Chinese and Egyptians burned oil for lighting.
Before the 1850s, Americans often used whale oil for light. When whale oil became scarce, people began looking for other oil sources. In some places, oil seeped naturally to the surface of ponds and streams. People skimmed this oil and made it into kerosene. Kerosene was commonly used to light America’s homes before the arrival of the electric light bulb.
As demand for kerosene grew, a group of businessmen hired Edwin Drake to drill for oil in Titusville, Pennsylvania. After much hard work and slow progress, he discovered oil in 1859. Drake’s well was 69.5 feet deep, very shallow compared to today’s wells.
Drake refined the oil from his well into kerosene for lighting. Gasoline and other products made during refining were simply thrown away because people had no use for them.
In 1892, the horseless carriage, or automobile, solved this problem, since it required gasoline. By 1920, there were nine million motor vehicles in this country and gas stations were opening everywhere.

Producing Oil

Although research has improved the odds since Edwin Drake’s days, petroleum exploration today is still a risky business. Geologists study underground rock formations to find areas that might yield oil. Even with advanced methods, only about 44 of every 100 exploratory wells find oil. The rest come up dry.
When oil is found, a petroleum company brings in a 50 to 100-foot drilling rig and raises a derrick that houses the tools and pipes that go into the well.
Today’s oil wells average 6,000 feet deep and may sink below 20,000 feet. The average well produces 11.3 barrels of oil a day.
To safeguard the environment, oil drilling and oil production are regulated by state and federal governments. Oil companies must get permission to explore for oil on new lands. Many experts believe that 85 percent of our remaining oil reserves are on land owned by the federal government. Oil companies lease the land from the federal government, which, in return, receives rental payments for the land as well as percentage payments from each barrel of oil.

Top Producers

Texas produces more oil than any other state. The other top producing states are Alaska, California, Louisiana, and Oklahoma. In all, 31 states produce petroleum.

From Well to Market

We cannot use crude oil in the state it's in when it comes out of the ground. The process is a little more complicated than that. So, how does thick, black crude oil come out of the ground and eventually get into your car as a thin, amber-colored liquid called gasoline?

Oil Refineries

Oil’s first stop after being pumped from a well is an oil refinery. A refinery is a plant where crude oil is processed. Sometimes, refineries are located near oil wells, but usually the crude oil has to be delivered to the refinery by ship, barge, pipeline, or train.
After the crude oil has reached the refinery, huge round tanks store the oil until it is ready to be processed. Tank farms are sites with many storage tanks.
An oil refinery cleans and separates the crude oil into various fuels and by-products. The most important one is gasoline. Some other petroleum products are diesel fuel, heating oil, and jet fuel.
Refineries use many different methods to make these products. One method is a heating process called distillation. Since oil products have different boiling points, the end products can be distilled or separated. Asphalts have a higher boiling point than gasolines, allowing the two to be separated.
Refineries have another job. They remove contaminants from the oil. A refinery removes sulfur from gasoline, for example, to increase its efficiency and to reduce air pollution. Nine percent of the energy in the crude oil is used to operate the refineries.

Shipping Oil Products

After processing at the refinery, gasoline and other petroleum products are usually shipped across the country through pipelines. There are about 230,000 miles of pipelines in the United States. Pipelines are the safest and cheapest way to move large quantities of petroleum across land.
Pump stations, which are spaced 20 to 100 miles apart along the underground pipelines, keep the petroleum products moving at a speed of about five miles per hour. At this rate, it takes 15 days to move a shipment of gasoline from Houston, Texas to New York City.

Distribution

Companies called jobbers handle the wholesale distribution of oil. There are 15,000 jobbers in the U.S., and they sell just about everything that comes out of a barrel of crude oil. Jobbers fill bulk orders for petroleum products from gasoline stations, industries, utility companies, farmers, and other consumers.
The final link in the chain is the retailer. A retailer may be a gasoline station or a home heating oil company. The last link is when you pump gasoline into your car, and the engine converts the gasoline’s chemical energy into mechanical energy to make your car move!

Demand for Oil

Since World War II, petroleum has replaced coal as the United States’ leading source of energy. Petroleum supplies more than 38 percent of the energy used in the United States. (Coal and natural gas each supply about 22 percent of our energy needs.)
Americans use about 18 million barrels of oil (more than 750 million gallons) every day of the year. And experts say we will be using more and more oil, especially for transportation, in the coming years.
Even now, we use 28 percent more oil for transportation than we did in 1973, when the first oil crisis hit the United States. This is true even though today’s automobiles get more than 1.7 times as many miles to the gallon as their 1970s counterparts. There are 60 percent more vehicles on the road today than in 1973. Today, we use about two out of every three barrels of oil to keep us on the move.
Americans use almost 18.2 million barrels of oil (more than 750 million gallons) every day of the year. And experts say we will be using more and more oil, especially for transportation, in the coming years. Even now, we use 26 percent more oil for transportation than we did in 1973, when the first oil crisis hit the United States. This is true even though today's automobiles get more than 1.7 times as many miles to the gallon as their 1970s counterparts. There are 58 percent more vehicles on the road today than in 1973. Today, we use about two out of every three barrels of oil to keep us on the move.

Imported Oil

To satisfy our appetite for petroleum, the United States has become increasingly dependent upon other countries for petroleum. Today, we purchase more than two-thirds of our petroleum from other countries.
Americans know this dependence can be dangerous. We were first alerted to the danger in 1973 when some Arab countries stopped shipping oil (called an embargo) to the United States. These countries belonged to an international trade group called the Organization of Petroleum Exporting Countries or OPEC for short.
OPEC members try to set production levels for petroleum. As a rule, the less oil they produce, the higher the price of oil on the world market. The OPEC countries don’t always agree. Some OPEC countries want to produce less oil to raise prices. Other OPEC countries want to flood the market with petroleum to reap immediate returns.
The next shock came in 1978-79 when the Iranian Revolution cut off oil production. Again, world oil prices raced up. Our most recent crisis was the Persian Gulf War. Iraq invaded Kuwait, and again, Americans worried about oil shortages and skyrocketing oil prices. The U.S. has taken some steps to prevent another big oil crisis. For one thing, the U.S. has about a three-month supply of oil tucked away in the Strategic Petroleum Reserve (SPR). Established in 1975, the SPR is only to be tapped during an energy emergency. The SPR was first used in January 1991, during the Persian Gulf Crisis.
The United States has also turned to non-Arab and non-OPEC countries for oil imports. Today, we import much of our oil from Canada and Mexico. This is good for us because we have friendly relations with our neighbors, and because the oil doesn’t have to be shipped so far. Still, the amount of oil that we can import from Canada and Mexico is limited. By law, Mexico can only export half the oil it produces to the United States.
Even with the SPR and imports from friendly, non-OPEC countries, U.S. oil supply is not totally secure. We buy almost half our imported oil from OPEC countries, a third from Arab countries.
Some economists believe the United States is setting itself up for another oil crisis. Other analysts say a true oil shock—like those of the 1970s—is unlikely because the producing nations don’t want to drive their customers away or encourage a shift to other forms of energy.
Still, there are more steps we can take to help ensure our energy security. Depending on whom you talk to—whether an oil company representative or an environmentalist—opinions vary on the one or more steps we should take. Some experts believe we should decrease our demand for oil through increased conservation. Others say we should increase oil production and exploration in the United States, particularly in the Arctic National Wildlife Refuge (ANWR) in northern Alaska. Others say we should use alternative fuels, especially for transportation. Some experts believe we will need to do all three to avert another oil crisis.

Offshore Oil Reserves

There are rich deposits of petroleum and natural gas on the outer continental shelf (OCS), especially off the Pacific coasts of California and Alaska and in the Gulf of Mexico. Thirty basins have been identified that could contain enormous oil and gas reserves. It is estimated that 30 percent of undiscovered U.S. gas and oil reserves are contained in the OCS.
Today, there are more than 4,000 drilling platforms, servicing thousands of wells. OCS production supplies approximately 30 percent of the nation’s natural gas production and 24 percent of its oil production. Most of the active wells are in the Central and Western Gulf of Mexico, with additional wells off the coast of California.
Although there are no producing wells in other areas, there is believed to be significant oil potential in the Beaufort Sea off Alaska, as well as natural gas potential in the Eastern Gulf of Mexico and in certain basins off the Atlantic Coast.
On December 31, 1997, President Clinton excluded the Pacific OCS, the North Atlantic and North Aleutian areas, and parts of the Eastern Gulf of Mexico from energy development until the year 2007.
Offshore production is costly—many times as expensive as land-based production. To reach oil buried in shallow water, drilling platforms stand on stilt-like legs that are imbedded in the ocean floor. These huge platforms hold all the drilling equipment needed, as well as housing and storage areas for the work crews. Once the well has been drilled, the platforms also hold the production equipment.
Floating platforms are used for drilling in deeper waters. These self-propelled vessels are anchored to the ocean bottom with huge cables. Once the wells have been drilled from these platforms, the production equipment is lowered to the ocean floor and sealed to the well casings to prevent leakage. Wells have been drilled in 10,000 feet of water using these floating rigs.

Oil Prices

Most of the world moves on petroleum—gasoline for cars; jet fuel for planes; diesel fuel for trucks. Then there is petroleum for running factories or manufacturing goods. That’s why the price of oil is so important. In 1998, the price of a barrel of oil averaged dropped as low as $8 a barrel, then in 2000 the price shot up to over $35. We even tapped into the Strategic Oil Reserve.
Low oil prices are good for the consumer and the economy, acting as a check on inflation. The oil industry, however, does not prosper during periods of low oil prices. Oil industry workers lose their jobs, many small wells are permanently sealed, and the exploration for new oil sources drops off.
Low oil prices have another side effect. People use more petroleum products when crude oil is cheap. We buy bigger cars and drive more miles.

Oil and the Environment

In the United States, we use more petroleum than any other energy source. Petroleum products—gasoline, fertilizers, plastics, and medicines—have brought untold benefits to Americans and the rest of the world. We depend on these products, and, as consumers, we demand them. But there is a flipside— petroleum production, distribution and consumption can contribute to air and water pollution.
Drilling for oil can disturb fragile ecosystems. Transporting oil can endanger wildlife and the environment if it spills into rivers or oceans. Leaking underground storage tanks can pollute groundwater and create noxious fumes. Processing oil at the refinery can contribute to air and water pollution. Burning gasoline to fuel our cars contributes to air pollution. Even the careless disposal of waste oil drained from the family car can pollute rivers and lakes.
Many advances have been made in protecting the environment since the passage of the Clean Air Act in 1970. Oil companies have redesigned their refineries to reduce emissions into the air and water. Gasolines have been reformulated to burn cleaner, dramatically cutting the levels of lead, nitrogen oxide, carbon monoxide, and hydrocarbons released into the air.
The production, transportation, distribution, and consumption of petroleum are strictly regulated to minimize the negative effects on the environment.
Our increasing dependence on petroleum presents a continuing challenge. The future must balance the growing demand for petroleum products with protection of the global environment.
About Petroleum is courtesy of the National Energy Education Development (NEED) Project. The mission of NEED is to promote and energy conscious and educated society by creating effective networks of students, educators, business, government and community leaders to design and deliver objective, multi-sided education programs. NEED serves as the energy education component of NOIA's Public Affairs Action Plan. For more information contact the NEED Project at http://www.need.org

alkanes, alkenes and alkynes

alkanes, alkenes and alkynes


Of the various chemical elements that we know .... there is an element whose scope is very broad and very deep discussion on the CARBON. Carbon has an atomic number of 6 so the number of electrons is also 6 .... with configuration 6C = 2, 4. This can be seen from the electron configuration C atom has four valence electrons (electrons in the outer shell) ..... To obtain 8 electrons (octet) in the outermost shell (valence electrons) needs 4 electrons so that each search valence electrons with the atomic electron pairs -other atom. The specificity of the carbon atom is its ability to bind to other carbon atoms forming the carbon chain. Forms of carbon rantai2 the simplest hydrocarbon. Hydrocarbons are composed of two elements, namely hydrogen and carbon.
Based on the number of other C atoms bonded to one C atom in the carbon chain, the C atom is divided into:
a. Primary C atom, the C atom that binds the C atom to another.b. Secondary C atom, the C atom bound to two other C atoms.c. Tertiary C atom, the C atom that binds the other three C atoms.d. Kwarterner C atoms, the atom C that bind to four other C atoms.


• primary C atom, C atom number 1, 7, 8, 9 and 10 (green)• secondary C atom, C atom number 2, 4 and 6 (blue)• tertiary C atom, C atom number 3 (yellow)• kwarterner C atom, C atom number 5 (red)
Based on the form of carbon chain:
• Hydrocarbons aliphatic hydrocarbons with chain = straight / open saturated (single bond / alkanes) and unsaturated (double bond / alkene or alkyne).• Hydrocarbons = alicyclic hydrocarbons with chain circular / closed (ring).• Aromatic Hydrocarbons = hydrocarbons with chain circular (ring) having a single bond between atoms C and dual alternately / alternating (conjugated)
Later in this article I discuss the limit of open-chain hydrocarbons (aliphatic) only ....Based on the existing bonds in the C chain, aliphatic hydrocarbons distinguished by:1. Alkanes (CnH2n +2)2. Alkenes (CnH2n)3. Alkynes (CnH2n-2)
Description: n = 1, 2, 3, 4, etc. .......
Alkanes (Paraffin)
is its hydrocarbon chain C consists of only a single covalent bonds only. often referred to as saturated hydrocarbons .... as the number of hydrogen atoms in the molecule tiap2 maximum. Understanding Alkanes nomenclature is vital, as the basis for naming senyawa2 other carbon.
Properties of Alkanes1. Saturated hydrocarbons (no bond C atom duplicate so its maximum number of H atoms)2. Called paraffin as affinity groups small (little affinity)3. It is difficult to react4. Form Alkanes with a chain C1 - C4 is a gas at room temperature, C4 - C17 is a liquid at ambient temperature and> C18 is a solid at room temperature5. Boiling point is higher for C elements ... and if it increases the number of C atoms together so that branches have a lower boiling point6. Solubility properties: easily soluble in non-polar solvents7. Density rose with increasing the number of elements of C8. Is a major source of natural gas and petroleum (crude oil)General formula CnH2n +2
Homologous series alkanes
Homologous series is a group / groups of carbon compounds with the same general formula, have similar properties and between ethnic groups have different berturutannya CH2 or in other words an open chain with no branches or branches with the same number of branches.
The properties of the homologous series of alkanes:o Have similar chemical propertieso Has the same general formulao The difference between the two tribes Mr berturutannya at 14o The longer the carbon chain, the higher the boiling point
n Formula Name
1. CH4 = methane2. C2H6 = ethane3. C3H8 = propane4. Butane C4H10 =5. C5H12 = pentane6. C6H14 = hexane7. C7H16 = heptane8. Octane C8H18 =9. C9H20 = nonana10. C10H22 = decane11. C11H24 = undekana12. C12H26 = dodecane
TATA NAME alkanes
1. Alkane name is based on the longest C chain as the main chain. If there are two or more chains are longest then selected the highest number of branches2. Branch C is a chain attached to the main chain. alkananya name written in front of the number and the name of the branch. Branch name matches the name alkanes by replacing the suffix with the suffix ana il (alkyl).3. If there are several branches of the same, then the name of the branch that is the same amount of C mentioned once but comes with a prefix that states the amount of the entire branch. The atomic number C where the branch is bound to be written as an existing branch (which is written numbers = number prefix is ​​used), which is at = 2, tri = 3, tetra = 4, penta = 5 and so on.4. For a number of branches of C is different sorted in alphabetical order (first from methyl ethyl).5. Branch number was calculated from the end closest to the main chain with branches. If the location of the nearest branch with both starting from the same:• Branch first alphabet sequence (first of methyl ethyl)• Branches are more numerous (two first branches of the branch)
Example:What is the name idrokarbon below?


The first time we set the main chain ..... the main chain is the longest chain:


main chain is in the red box ...... Why?? you try to look at the left side, when the main chain is straight (line putus2) then sama2 will increase 2 atom C but will only lead to one branch (the part you turn down) .... whereas when we steered down there will be 2 branches (Rule No. 1). Now you try to look to the right, the explanation is more simple .... when a straight main chain (line putus2) only increased by one C atom whereas when turned down it will grow 2 atom C. So it may be a series of major chains belak-turn and not be straight ...... origin still in one continuous sequence with no branches.
The remaining carbon chain of the chain is the branch .....


look there are 3 branches namely 1 and 2 methyl ethyl branches numbering ..... we select the smallest number:
• if the end of the left side of the main chain ethyl C atom is located in the main chain and methyl number 3 is located in the main chain C atom number 2 and 6• if the end of the right of the main chain ethyl C atom is located in the main chain and methyl number 6 in the main chain C atom numbers 3 and 7
conclusions about sort of the tip of the left .....
Sequence naming: branch number - nana branch - the name of the parent chain
so his name: 3 ethyl dimethyl octane 2.6

 ethyl branch called earlier than methyl because his first name alphabetically first (alphabet "e" from the first "m"). because there are two methyl branches then simply called once plus the prefix "in" means "two". because the main chain consists of 8 main chain atom C then named: octane.
Alkanes form skeletal structures undergo condensation sometimes ..... for example:


CH3 (green) is the end of the chainCH2 (blue) is the straight-chain tenganhCH (orange color) branching threeC (red) four branching
Usefulness alkanes, as:
• Fuel• Solvents• Sources of hydrogen• Lubricants• The raw material for other organic compounds• Raw materials industry
Alkenes (Olefins)
an unsaturated hydrocarbon compound that has one double bond 2 (-C = C-)
Properties of Alkenes• Hydrocarbons unsaturated double bonds• alkene called olefins (oil forming)• more active physiological properties (as sleeping pills -> 2-methyl-2-butene)• Properties with Alkanes, but more reactive• Properties: colorless gas, can be burned, peculiar smell, explosive in the air (at a concentration of 3-34%)• There is the ordinary coal gas in the process of "cracking"General formula CnH2n
NAME of alkenes
almost the same as naming Alkanes with a difference:• The main chain must contain the double bond and selected the longest. Name the major chains are also similar to alkanes by replacing the suffix-ana-ene. So the selection of the longest chain of C atoms starting from C dual to the right and left and the right and left selected the longest.• Numbers written bond position in front of the main chain and is calculated from the tip to the location of the double bond C its smallest sequence number.• Sequence number position as branch chain numbering sequence fagots main chain.Example:


calculation of C atoms in the main chain starting from the left side of the double bond bond .... there is only one option bond while the right there are two options, namely the first straight and bend down .... kedua2nya sama2 adding 4 C atoms, but when it turns produced only one first down when a straight branch while causing two branches.
So his name: 3 ethyl 4 methyl 1 pentena
1 pentena can be replaced by n-pentena or special bonds at number one should not be written .... so the name quite: pentena. Branch number equal to the number sequence sorted double bond. In question at the top of the right end ....
Uses Alkenes as:• Can be used as an anesthetic (mixed with O2)• To ripen fruit• industrial raw materials plastics, synthetic rubber, and alcohol

alkyne

an unsaturated hydrocarbon compounds having one double bond 3 (-C C-). The nature is the same as alkenes but more reactive.

General formula CnH2n-2

   Tata same name with Alkenes .... but the suffix-ene-una replaced

Uses alkyne as:

     ethyne (acetylene = C2H2) is used to weld iron and steel.
     for lighting
     Synthesis of other compounds.